At the BBC
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Disc1
| 1 | Stronger Than Me (live on Later… with Jools Holland / 2003) | Amy Winehouse | 3:50 |
| 2 | Take the Box (live From the Mercury Prize Awards / 2004) | Amy Winehouse | 3:50 |
| 3 | Teach Me Tonight (live on Jools Holland Hootenanny / 2004) | Amy Winehouse feat. Jools Holland | 3:18 |
| 4 | Rehab (live on Later… with Jools Holland / 2006) | Amy Winehouse | 3:45 |
| 5 | Tenderly (live on Later… with Jools Holland / 2006) | Amy Winehouse feat. Jools Holland | 1:13 |
| 6 | Tears Dry on Their Own (live on Later… with Jools Holland / 2006) | Amy Winehouse | 3:24 |
| 7 | Monkey Man (live on Jools Holland Hootenanny / 2006) | Amy Winehouse feat. Jools Holland | 3:19 |
| 8 | I Heard It Through the Grapevine (live on Jools Holland Hootenanny / 2006) | Amy Winehouse feat. Paul Weller & Jools Holland | 3:54 |
| 9 | Don’t Go to Strangers (live on Jools Holland Hootenanny / 2006) | Amy Winehouse feat. Paul Weller & Jools Holland | 4:36 |
| 10 | Love Is a Losing Game (live From the Mercury Prize Awards / 2007) | Amy Winehouse | 2:34 |
Disc2
| 1 | Know You Now (live at the Leicester Summer Sundae / 2004) | Amy Winehouse | 3:55 |
| 2 | Fuck Me Pumps (live From T in the Park / 2004) | Amy Winehouse | 3:41 |
| 3 | In My Bed (live From T in the Park / 2004) | Amy Winehouse | 4:37 |
| 4 | October Song (live From T in the Park / 2004) | Amy Winehouse | 3:42 |
| 5 | Rehab (live Pete Mitchell, BBC Radio session / 2006) | Amy Winehouse | 3:58 |
| 6 | You Know I’m No Good (live Jo Whiley, BBC live Lounge session / 2007) | Amy Winehouse | 3:26 |
| 7 | Just Friends (live BBC Radio 2 Big Band Special / 2009) | Amy Winehouse | 3:17 |
| 8 | Love Is a Losing Game (live on Later… with Jools Holland / 2009) | Amy Winehouse | 2:49 |
| 9 | Tears Dry on Their Own (live Jo Whiley, BBC live Lounge session / 2007) | Amy Winehouse | 3:11 |
| 10 | Best Friends, Right (live at the Leicester Summer Sundae / 2004) | Amy Winehouse | 3:03 |
| 11 | I Should Care (live From the Stables / 2004) | Amy Winehouse | 3:39 |
| 12 | Lullaby of Birdland (live From the Stables / 2004) | Amy Winehouse | 2:34 |
| 13 | Valerie (live Jo Whiley, BBC live Lounge session / 2007) | Amy Winehouse | 3:51 |
| 14 | To Know Him Is to Love Him (live Pete Mitchell, BBC Radio session / 2006) | Amy Winehouse | 2:33 |
BBC One Sessions
| 1 | Know You Now | Amy Winehouse | 3:13 |
| 2 | Tears Dry on Their Own | Amy Winehouse | 3:27 |
| 3 | You Know I’m No Good | Amy Winehouse | 4:15 |
| 4 | Just Friends | Amy Winehouse | 3:13 |
| 5 | He Can Only Hold Her | Amy Winehouse | 3:15 |
| 6 | I Heard Love Is Blind | Amy Winehouse | 3:20 |
| 7 | Rehab | Amy Winehouse | 3:38 |
| 8 | Take the Box | Amy Winehouse | 3:30 |
| 9 | Some Unholy War | Amy Winehouse | 3:21 |
| 10 | Back to Black | Amy Winehouse | 3:54 |
| 11 | Valerie | Amy Winehouse | 3:35 |
| 12 | Addicted | Amy Winehouse | 2:58 |
| 13 | Me & Mr Jones | Amy Winehouse | 2:41 |
| 14 | Monkey Man | Amy Winehouse | 2:51 |